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This paper evaluates the total lifecycle impacts for hauling freight long distances over land in the United States. The dominant modes of surface freight transport in the United States are large motor trucks (tractor-semitrailer combinations) and trains. These vehicles account for a significant portion of the transportation sector's petroleum usage and atmospheric emissions (among which nitrogen oxides and particulate matter are especially important). The objective of this paper is to evaluate the potential for reductions in energy use (in particular, petroleum use) and atmospheric emissions that result from freight transport, possibly as the result of research and development on improved technology or alternative fuels, such as Fischer-Tropsch diesel and natural gas, or from mode shifts in competitive markets. The impacts examined include energy use, both in toto and the petroleum fraction, and emissions of greenhouse gases and nitrogen oxides and particulate matter.

Their high fuel economy is making light-duty vehicles with spark-ignition direct-injection (SIDI) engines attractive. However, the implications for exhaust emissions and the effects of fuel quality on emissions are not clear for this type of engine. A Mitsubishi Legnum with a 1.8-L GDI™ engine was tested on federal test procedure (FTP) and highway fuel economy cycles. The results were compared with those for a production Dodge Neon vehicle with a 2.0-L port fuel-injection (PFI) engine. The Mitsubishi was tested with Indolene, Amoco Premium Ultimate, and a low-sulfur gasoline. The Neon was tested only with Indolene. Both engine-out and tailpipe emissions were measured. Second-by-second emissions and hydrocarbon speciation were also evaluated. The SIDI engine provided up to 24% better fuel economy than the PFI engine on the highway cycle. Tailpipe emissions of oxides of nitrogen (NOx) from the SIDI vehicle using low-sulfur fuel were 40% less than those when using Indolene.

Preliminary research in our laboratory has demonstrated that boric acid is an effective lubricant with an unusual capacity to reduce the sliding friction (providing friction coefficients as low as 0.02) and wear of metallic and ceramic materials. More recent studies have revealed that water or methanol solutions of boric acid can be used to prepare strongly bonded layers of boric acid on aluminum surfaces. It appears that boric acid molecules have a strong tendency to bond chemically to the naturally oxidized surfaces of aluminum and its alloys and to make these surfaces very slippery. Recent metal-formability tests indicated that the boric acid films applied to aluminum surfaces worked quite well, improving draw scale performance by 58 to 75%.

Many problems are associated with applying standardized vehicle test methods, such as the Federal Test Procedure (FTP), to hybrid electric vehicles (HEVs). Since 1992, the Society of Automotive Engineers' (SAE's) HEV Test Procedure Task Force has been working on developing a standard procedure for HEV testing (Draft SAE J1711). Because the current draft requires considerable knowledge of the vehicle's response to the test cycles, still has unresolved problems, and is too lengthy, Argonne National Laboratory (ANL) uses portions of past J1711 drafts in combination with concepts developed through many HEV tests (over 50 to date) for its HEV competition testing. Successful vehicle characterization was achieved at the 1997 FutureCar Challenge competition by characterizing each vehicle's individual operational modes in such a way that the elements of the FTP and Federal Highway Test were satisfied.

A two-stage Delphi study was conducted to collect information that would enable a technical and economic assessment of electric (EV) and hybrid electric (HEV) vehicles. The first-stage worldwide survey was completed in fall 1994 while the second-stage was completed by summer 1995. The paper reports results from the second round of the survey and the major differences between the two rounds. This second-stage international survey obtained information from 93 expert respondents from the automotive technology field. The second stage response provided the following key results. EVs will penetrate the market first followed by internal combustion engine powered HEVs while gas turbine and fuel cell powered HEVs will not have any significant penetration until after 2020. By 2020 EVs and internal combustion engine powered HEVs are projected to have approximately a 15% share of the new vehicle market.

Disposal of automobile shredder residue (ASR), remaining from the reclamation of steel from junked automobiles, promises to be an increasing environmental and economic concern. Argonne National Laboratory (ANL) is investigating alternative technology for recovering value from ASR while also, it is hoped, lessening landfill disposal concerns. Of the ASR total, some 20% by weight consists of plastics. Preliminary work at ANL is being directed toward developing a protocol, both mechanical and chemical (solvent dissolution), to separate and recover polyurethane foam and the major thermoplastic fraction from ASR. Feasibility has been demonstrated in laboratory-size equipment.

Analytical studies of oxygen-enriched diesel engine combustion have indicated the various benefits as well as the need for using cheaper fuels with water addition. To verify analytical results, a series of single-cylinder diesel engine tests were conducted to investigate the concepts of oxygen enriched air (OEA) for combustion with water emulsified fuels. Cylinder pressure traces were obtained for inlet oxygen levels of 21% to 35% and fuel emulsions with water contents of 0% to 20%. Data for emulsified fuels included no. 2 and no. 4 diesel fuels. The excess oxygen for the tests was supplied from compressed bottled oxygen connected to the intake manifold. The cylinder pressure data was collected with an AVL pressure transducer and a personal computer-based data logging system. The crank angle was measured with an optical encoder. In each data run, 30 consecutive cycles were recorded and later averaged for analysis.

Safety issues and current transport (shipment and b-vehicle use) and environmental regulations applicable to sodium-sulfur batteries for electric vehicles are summarized, and an assessment technique is suggested for evaluating potential hazards relative to commonly accepted risks. It is found that shipment regulations do not directly apply to sodium-sulfur batteries. Disposal hazards need to be quantified and decommissioning procedures need to be developed to comply with the environmental regulations. The risk assessment could be used to help commercialize sodium-sulfur and other advanced batteries in electric vehicles.

The performance of advanced Zn/Br2, LiAl/FeS, Na/S, Ni/Fe, and Fe/Air batteries in electric vans was compared to that of tubular lead-acid technology. The MARVEL computer analysis system evaluated these batteries for the G-Van and IDSEP vehicles over two driving schedules. Each of the advanced batteries exhibited the potential for major improvements in both range and life cycle cost compared with tubular lead-acid. A sensitivity analysis revealed specific energy, battery initial cost, and cycle life to be the dominant factors in reducing life cycle cost for the case of vans powered by tubular lead-acid batteries.

A methodology has been developed for identifying the combination of battery characteristics which lead to least-cost electric vehicles. Battery interrelationships include specific power vs, specific energy, peak power vs. specific energy and DOD, cycle life vs. DOD, cost vs. specific energy and peak power, and volumetric and battery size effects. The method is illustrated for the “second car” mission assuming lead/acid batteries. Reductions in life-cycle costs associated with future battery research breakthroughs are estimated using a sensitivity technique. A research prioritization system is described.